Texas,
I don't know why, but last night this pic appeared to have about a 4 ? ? to 5? opening.
Shadowing, my old eyes, I don't know?) I looked at it much closer this evening. It does appear to have 3" of reveal on each side of the hole. From a 12 X12, that would leave a 6" opening. I knew that you had a 6" flu. But, at the time, this transition brick appeared to me as a bottleneck. Six inches is fine for a 36" oven. My apologies

As for as the interlocking of the corners for a vent/flu transition goes, that is just my humble opinion. My ideas for how one should be built require deeper entries. That is not a popular subject for this site

If all that is required of your great or great-great grandkids, (in order to keep your masterpiece funtional), is to touch up the entry..................so what

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