I really respect David's opinion, so you have a couple different schools of thought. I may have mis-spoken regarding the rectangular base to a round chimney to meaning that square chimney is not as effective as a round chimney. Here is a clip that I based my comments on from the US's fireplace manufacturer society.
"Round flue pipes vent a lot better than square flue pipes because the products of combustion rifle or spiral up the round pipe. Often, a square edge clay chimney liner is not even fully used because the gases will still spiral up the pipe as much as they possibly can"
"Round flue pipes vent a lot better than square flue pipes because the products of combustion rifle or spiral up the round pipe. Often, a square edge clay chimney liner is not even fully used because the gases will still spiral up the pipe as much as they possibly can"
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