Portland cement-based mortar should be fine for your chimney--you could add lime and fireclay to do the full "homebrew" refractory mortar, but likely for the transition to your flue, even plain mortar would be fine. Homebrew refractory is 3:1:1:1 sand
ortland:lime:fireclay by volume. If you don't have (or want to use) lime or fireclay, just skip those parts (standard brick mortar being 3:1 sand and portland cement). You may have this in mind, but just want to flag that to get proper draw, the flue for a 36"/90cm diameter oven needs to be at least a 6"/15cm diameter round, or equivalent cross-sectional area (~28 square inches/180cm^2). Based on brick widths, looks like your opening right now is around 4.5" x 13.5", which is plenty, but be careful as you narrow it to meet the flue that you don't shrink it too much.





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