I found this on a UK flue suppliers site today:
Twin Wall Flue FAQ's (picture shows double wall with insulation but doesn't state Class A - however, the same 50mm clearance is recommended)
How hot does twin wall flue get?
Twin wall flues will heat up when in use as they transport the hot stove gases away from the appliance, the outer part of the flue can be over 90o C or 194o F. The temperature of the twin wall flue will vary depending on:
- KW of the stove.
- What fuel is being burnt.
- Length of the flue (the base of the flue will be hotter than the top).
- Temperature outside.
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